The basic geometry is trigonal planar with 120° bond angles, but we see that the double bond causes slightly larger angles (121°), and the angle between the single bonds is slightly smaller (118°).Īlthough in both formaldehyde (H 2CO) and ammonia (NH 3) examples exact bond angles are given, you are not expected to memorize the bond angles in EVERY molecule. This molecule has regions of high electron density that consist of two single bonds and one double bond. The H–N–H bond angles in NH 3 are slightly smaller than the 109.5° angle in a regular tetrahedron because the lone pair-bonding pair repulsion is greater than the bonding pair-bonding pair repulsion.Ĭonsider formaldehyde, H 2CO, which is used as a preservative for biological and anatomical specimens. Again, there are slight deviations from the ideal because lone pairs occupy larger regions of space than do bonding electrons. The ideal bond angles in a trigonal pyramid are based on the tetrahedral electron pair geometry. In the ammonia molecule, the three hydrogen atoms attached to the central nitrogen are not arranged in a flat, trigonal planar molecular structure, but rather in a three-dimensional trigonal pyramid with the nitrogen atom at the apex and the three hydrogen atoms forming the base. Lone pair > triple bond > double bond > single bond The order of sizes from largest to smallest is: A lone pair of electrons occupies a larger region of space than the electrons in a triple bond in turn, electrons in a triple bond occupy more space than those in a double bond, and so on. This order of repulsions determines the amount of space occupied by different regions of electrons. Lone pair-lone pair > lone pair-bonding pair > bonding pair-bonding pair The order of electron-pair repulsions from greatest to least repulsion is: VSEPR theory predicts these distortions by establishing an order of repulsions and an order of the amount of space occupied by different kinds of electron pairs. (c) The actual bond angles deviate slightly from the idealized angles because the lone pair takes up a larger region of space than do the single bonds, causing the HNH angle to be slightly smaller than 109.5°.Īs seen in Figure 2, small distortions from the ideal angles for a given electron-pair geometry can result from differences in repulsion between various regions of electron density. ![]() (b) The trigonal pyramidal molecular structure is determined from the electron-pair geometry. (a) The electron-pair geometry for the ammonia molecule is tetrahedral with one lone pair and three single bonds. ![]() VSEPR structures like this one are often drawn using the wedge and dash notation, in which solid lines represent bonds in the plane of the page, solid wedges represent bonds coming up out of the plane, and dashed lines represent bonds going down into the plane. The molecular structure of the methane molecule, CH 4, is shown with a tetrahedral arrangement of the hydrogen atoms. One of these regions, however, is a lone pair, which is not included in the molecular structure, and this lone pair influences the shape of the molecule (Figure 2). On the other hand, the ammonia molecule, NH 3, also has four electron pairs associated with the nitrogen atom, and thus has a tetrahedral electron-pair geometry. ![]() The electron-pair geometries will be the same as the molecular structures when there are no lone electron pairs around the central atom, but they will be different when there are lone pairs present on the central atom.įor example, the methane molecule, CH 4, which is the major component of natural gas, has four bonding pairs/domains of electrons around the central carbon atom the electron-pair geometry is tetrahedral, as is the molecular structure (Figure 1). ![]() The structure that includes only the placement of the atoms in the molecule is called the molecular structure. We differentiate between these two situations by naming the geometry that includes all electron pairs the electron-pair geometry. So all central atoms have one of the defined geometries above (linear, → octahedral) and then if it has a number of lone pairs greater than zero it has a different molecular structure/shape. It shows the overall shape that the bonds make within a structure that still abides by a set electron-pair geometry defined above. Molecular structure/shape describes the location of the atoms, not the electrons. The electron-pair geometries shown in the previous page describe all regions where electrons are located, bonds as well as lone pairs. It is important to note that electron-pair geometry around a central atom is not the same thing as its molecular structure/shape.
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When adding cameras on different channels from the NVR, the steps are the same as adding a single camera, just repeat the same steps to add with the same IP (the IP address of the NVR) address, and only need to pay attention to modifying the channel field of the URL. If you can’t find the corresponding model for Model settings, just use the first default *model, no modification is required, and the model is not required to be correct.Ĭ. Cameras with a resolution of 8MP and above can only use the sub-stream to live view, because when you use the Reolink protocol to add a camera, you actually use the RTMP protocol, while RTMP does not support the h.265.ī. Note: when you use Reolink protocol to add a camera, please pay attention to the following points.Ī. You can live view the camera on Blue Iris now. Type your camera’s username ( admin by default) and password in the URL, click OK. Make sure the RTSP and ONVIF port numbers are the same as your camera’s. Enter the camera IP address and password. Step 2: Choose Reolink as a protocol for the Make setting. Step 1: Launch Blue Iris, right-click to choose Add New Camera, and click OK to add a camera in LAN Method 2: Add the camera via Reolink protocol Enter the camera IP address and password, and make sure the RTSP and ONVIF port numbers are the same as your camera’s, click OK. Confirm Onvif protocol is selected by default for Make Setting. Launch Blue Iris, right-click to choose Add New Camera, and click OK to add a camera in LAN Method 1: Add the camera via ONVIF Protocol Manually ![]() ![]() Note: You can also open the ports via Reolink NVRs or via the web browser, see: How to Configure Reolink Ports Settings. After opening the ports, do not forget to Save your configurations. Note: TrackMix Wired LTE can only support this feature when using wired connection.īefore getting started, login to your device on the Reolink Client, go to Device Settings > Network > Advanced > Server settings to open relevant ports for the device. Applies to: All Reolink NVRs and cameras except all battery-powered cameras, E1 and Lumus. ![]() Many undeserving people are beaten down by life. The transition from seeking solace in life to seeking solace in death is beautiful and convincing.Īlong the way, the reader is reminded that less fortunate people have unexplored characters and stories that are often overlooked. Realistically, some people just have completely terrible lives. In many manga series, the character will experience the bad so that the good seems so much better when it comes. She endures the pain for a good future with her boyfriend, until.īeautiful. You'd think one would break down and cry a little when one get's hurt, but even after all the bad things happening to her, she persists. Except for the obvious sexual pleasure, she doesn't show emotions or thoughts for her current situation, except for the abortion scene and at the end. NOT FOR THE FAINT OF HEART.ĮDIT : I've noticed something. I'm disgusted, emotionally drained, sad as well as a little scared after reading this. TL DR :- One of the (surprisingly) saddest manga stories I've read as of writing this, and considering it is a hentai manga. It makes me scared that it happens to girls (and maybe even boys) in real life. Without spoiling anything, all the horrible things that happened before all combine to make a big punch in the gut, and to the heart, that you won't forget soon.ĥ. But Chapter 7 is when it separates itself from other hentai manga. And this continues on for 6 chapters, which is quite amazing to keep the reader engaging and disgusted at the same time.Ĥ. Even though they may seem cliched, it is still very hard to sit through. by the second chapter because of what was happening.ģ. I glance a quite many hentai manga, because reasons. But since it's a hentai manga, it's interrupted by a lot of sex scenes.Ģ. But the series of events and how they are unfolding and being presented, keeps the plot engaging. ![]() The "decent-into-living-hell" kind of one. So you now know it's "that" kind of story. * Then after hearing about ways to earn money by sex from her school friends, she gets into escorting, and that's when everything goes downhill.ġ. She gives into his charms, and accepts her as his boyfriend. He forces here into sex, even gives LSD to her, and hence afterwards, declares her his girlfriend. * She then meets a guy in a shop, who invites for a drink, and her wanting to be an "adult", goes there. she asks her mom to do some make-up and then she suddenly becomes the most attractive girl in the school. * Saki is a socially reclusive yet a very naiive girl, and when entering in high school, wants to become more social-able. Writing was nothing special, but was bearable. And it made the disgusting moments even more disgusting (in a good way, of course).Ģ. I'm not a manga reader(but an avid anime watcher), so this is still on of my early manga experiences.īefore moving to the crux, I'll address the technical things first.ġ. So, I happen to stumble upon this manga from a stupid Facebook page, and thought why not give it a go. ![]() a letter from a motor vehicle dealer confirming the manufacturer’s specifications for the empty weight.proof of the empty weight of the vehicle in kilograms excluding the load (if not already on the ownership) – you can get this from any government approved scale site, such as a garbage dump, cement company, vehicle inspection station.a complete bill of sale (if vehicle is not in your name).all general requirements to register your vehicle in Ontario.To register a personal use vehicle (for example, pick-up truck) in Ontario that was a commercial use vehicle in another province or country, you will need: For questions about retail sales tax exemptions, contact ServiceOntario at 41 ( GTA) or toll free at 1-80 (Canada).įind out where you can register a vehicle Personal vehicle that was commercial use outside of Ontario If you are becoming an Ontario resident, you can declare an exemption when you register the vehicle instead of paying the retail sales tax. Find out if your vehicle will be charged retail sales tax or HST. Most vehicles that are purchased privately in another Canadian province will be charged retail sales tax or HST at 13% when you register in Ontario. Pay retail sales tax or harmonized sales tax ( HST) A letter from a military commanding officer is no longer required. 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Military personnel can use their NDI 20 and NDI 21 Department of National Defence issued military identification cards to prove their name, signature and date of birth for vehicle transactions. a letter from leasing company authorizing the vehicle to be registered in Ontario.a letter from leasing company with RIN and VIN.If the vehicle is under a leasing agreement, you will need to provide either: Note: We now require proof of lease to register your out-of-province leased vehicle in Ontario. include your vehicle in the list of imported goods.complete the customs clearance Vehicle Import Form 1 from the Canada Border Service Agency website.complete all general requirements to register your vehicle in Ontario.When you register a vehicle from outside of Canada you must: There are different steps depending on where you are bringing the vehicle from. When you register a vehicle from out of the province, you must complete some extra steps. If you have a vehicle from outside Ontario that you would like to register in the province, you can register your vehicle at a ServiceOntario centre. ![]() The guides are different depending on your device so make sure you pick the correct one. If you haven’t already gained access to Fortnite on Android make sure you check out either of the following guides. In order to enable 2FA, do the following: Go to and log into your account. Note: If you play Fortnite from another device with another account Xbox for example, you should also make sure you have 2FA enabled on those accounts. With a lot of accounts getting hacked and then sold daily, Epic Games have decided to reward players who enable 2FA on their account with the ‘Boogie Down’ emote. Once you have enabled 2FA, you will see the new Boogie Down Emote added to your profile. How do I enable 2FA Go to the ACCOUNT page. On a side note, if you don’t have a strong account password, make sure you update your password while you are in account settings. Or if you chose Google Authenticator you'll need to use the app, which will give you a code, you need to enter before you will be signed in correctly. How to Backup Google Authenticator (Backup Google 2FA)įrom now on, whenever you sign into your Epic Games account on a new device, you'll be emailed a unique sign in code. Before you go ahead and enabled it, make sure you check out the following guide on making a backup of Google 2FA. ![]() On this page, click Password and Security. At the bottom you have two options, the first is to Enable an Authenticator App like Google Authenticator or Enable Email Authentication.Įither option will work fine, however, Google Authenticator is well known for being the most secure. Go to and sign into your account. Next, open Account Settings by hovering the mouse over your Username in the top right corner and selecting Account To begin adding 2FA to your Epic Games Fortnite account do the following. How Do You Get a Free Fortnite Emote? By Enabling Two Factor Authentication (2FA) That's How!įor some users the idea of adding 2FA to their account may seem difficult, however, it is one of the easiest things you can do. As we all know free stuff always gets people motivated. ![]() Als Belohnung für den aktiven Schutz deines Kontos wird dann das Boogie Down-Emote in Fortnite Battle Royale für dich freigeschaltet. A vast number of Fortnite users don’t, which Epic Games aims to reduce with this simple free offer. Schütze dein Konto, indem du 2FA aktivierst. Generally getting something for free has its drawbacks or catches, so most people a quite skeptical when something good comes around… However, in this instance, things are a little different as Epic Games is incentivizing a reason to add an extra layer of security to Fortnite accounts.Īlthough most people should already have 2FA enabled on all their accounts, Facebook, Instagram, WhatsApp, Steam, Epic Games, etc. If you don't fancy the Precision Mouse from Microsoft, Logitech's MX Master 3 is a stunning runner-up that's almost as good. It's the option if you desire a balance between cost and ergonomics, all while packing some handy features. Microsoft was able to pull ahead here by going with a compromise, which resulted in the Surface Precision Mouse. There are two mice that we love and were both so close to becoming our favorite, but one came out on top. Some folks prefer compact mice, while others enjoy ergonomics and extra functionality. There's no one mouse that's perfect for all Surface owners. ![]() With AAA batteries, you can get up to 18 months of use. The best part of the Pebble M350 is the battery life. It connects with Bluetooth or a dongle, though an adapter is required for the latter solution. While it's possible to throw it inside a laptop sleeve for easier carriage, this does mean it's not as comfortable to use, especially for longer periods. This Logitech pointer is best suited for the frequent traveler due to its low weight and thin dimensions. Our budget pick is the Logitech Pebble M350 Wireless, though it's still a capable mouse. Still, it's a superb mouse with an amazing accurate sensor. There's another drawback to the MX Master 2S in that there may be a slight rattle through use, and we found the mouse clicks rather loud. It's a little short on what Microsoft boasts with the Surface Precision Mouse. The downside is all this functionality needs power the mouse itself lasts up to 40 days on a charge, but this should be more than enough between top-ups through its Micro-USB port. Up to three PCs can be paired at the same time, with just the push of a button to switch between them (handy if you have more than one device in use at once). That's a feature not present on some wireless mice - the ability to switch between wireless modes. You have the choice to either use the supplied receiver (which can connect up to six devices) or Bluetooth. The Logitech MX Master 3 is the mouse for people who require a portable unit that does it all, replacing the older Logitech MX Master 2S. ![]() Since then, I switched back to World of Tanks that I grew up with for many years and hardly face any cheaters in it, although matchmaking is what it is if you ever played WoT before.DPI settings are decent but not outstanding EA/DICE also threw Battlefield out when they FAILED third-party servers and the ability for server moderators to play in the same game with others and communicate with players, also picking your own maps towards the end of a match is nice.ĮDIT: Forgot to also mention, you can already see it shake up EA themselves with shareholders in this link. THIS of course, is no longer "relevent" with the game industry which I think stagnates their games and forces people to go elsewhere. They announce at launch that there would be 5 DLCs in the coming months in the game. ![]() I felt EA/DICE threw the Battlefield series in the trash when they announced there would no longer be any DLC content where you buy Premium for the game. I did go back to Battlefield 4 which imo is one of the best Battlefield games out there (BF3 is still good, but I like BF4 more) that contains more dynamic features in it like the weather/Frostbite 3 where you can take down buildings (Siege of Shanghai etc, the dam on the other map, Operation Locker). Then I go back to Rainbow Six Siege in Ranked mode and there's cheaters in there as well.stopped playing that game as well as its frustrating in a competitive shooter. When they announced a couple months ago that there was going to be one last content update to Battlefield V to the game by June 2020, I stopped playing Battlefield V. 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Its quite a good website, straight to the point, It has a bit of everything, not a complete archive but you can find many full length videos. The number of videos aren’t high but if you be lucky you may find almost all videos of your favorite Onlyfan model there, The website need atleast 10x more contents to become practical. The website is focus more on VOD (videos on demands), Something like Onlyfans and Manyvids. It means when a video get deleted on their website, they dont remove the thumbnail and it sends you to some irrelevant videos. The bad about this website is their fake videos. You can find many full length porn videos there, This is the first to go for many people. ![]() I think its just a theme for daftsex as it shares same database and videos. This website is from same owner of Daftsex. ![]() Have many full length videos, have many half length videos as well that ruin the searching, You need to filter them out Update : The number of daily uploaded videos are shrinking, this is concerning as its an early sign of end of a tube website. Many full length videos from premium studios, Almost all legalporno videos are over there, They consider 360p as HD however some of their recent videos are in 720p and 1080p.Ībout 5000 videos get added to that website daily and half of them get deleted instantly or same day, Still you can find good full length videos there, Sometimes you are asked to upload a video in order to be able to download 720p or better quality. Website is slow in compare to other tube websites. Many premium videos get remove but they get re uploaded again Number of videos are limited, less than 20K. The website only allow 1 thread for downloading videos, After downloading the video change the file format from. Unique feature of this website is that it has full archive of those networks, It has even deleted scenes of brazzers and realitykings as well.ĪKA xy, When they change the domain most of videos were lost, but now videos get rarely removed. Many full length premium videos such as Brazzers, Realityking, Mofos, public agent and more. I gathered a list of top tube websites that have FULL length porn videos, most of famous tube websites such as xvideos, xhamster and pornhub only have short clip of premium porn videos, Below you can find list of those websites that always upload full-length and you can find the latest release there. ![]() A can then be generated which allows users to share their graphs and elect to be considered for staff picks. Users can create accounts and save the graphs and plots that they have created to them. ![]() Other functions like trigonometric and other transcendental functions, as well as the error function, factorial, statistical operations such as the normal distribution, chi-squared, the aforementioned regressions, and the random function, have also been introduced since 2020. Integrations to positive and negative infinity are supported, and series can also be raised to sufficiently high iterations. Calculus operations such as derivatives and integrals are also available, although direct limits are currently absent. It can also be used in several languages. In addition to graphing both equations and inequalities, it also features lists, plots, regressions, interactive variables, graph restriction, simultaneous graphing, piece wise function graphing, polar function graphing, two types of graphing grids – among other computational features commonly found in a programmable calculator. In September 2023, Desmos released a beta for a 3D calculator, which added features on top of the 2D calculator, including cross products, partial derivatives and double-variable parametric equations. In it, geometrical shapes can be made, as well as expressions from the normal graphing calculator, with extra features. In May 2023, Desmos released a beta for a remade Geometry Tool. Desmos Studio was spun off as a separate public benefit corporation focused on building calculator products and other math tools. In May 2022, Amplify acquired the Desmos curriculum and. The name Desmos came from the Greek word δεσμός which means a bond or a tie. As of September 2012, it had received around 1 million US dollars of funding from Kapor Capital, Learn Capital, Kindler Capital, Elm Street Ventures and Google Ventures. History ĭesmos was founded by Eli Luberoff, a math and physics double major from Yale University, and was launched as a startup at TechCrunch's Disrupt New York conference in 2011. Desmos is an advanced graphing calculator implemented as a web application and a mobile application written in TypeScript and JavaScript. |
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